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31.
32.
The main aim of this research was to assess the mercury transport from an estuarine basin with a background of anthropogenic contamination during a spring tidal cycle (year 2009) and compare it with two previous tidal cycles (years 1994 and 1999), as part of a long‐term monitoring program. Results showed that effective mercury transport occurs both in the dissolved and particulate fractions (0.18 and 0.20 kg per tidal cycle, respectively), and despite an overall decrease in environmental contamination, results more than double previous findings on particulate transport in the system. These findings result essentially from changes in the tidal prism (net export of 2 million m3 of water), given that both dissolved and particulate concentrations did not increase over time. Hydrodynamic simulations were performed to evaluate the effect of physical disturbance (dredging) and weather events (increased freshwater flow) in these processes, and results suggest the increased freshwater flow into the system as the main forcing function for the mercury transport increment. These results highlight the importance of long‐term monitoring programs, since despite an overall improvement in local contamination levels, the enhancement of transport processes through hydrological changes increases environmental pressure away from the contamination source. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
33.
The effects of climate change and population growth in recent decades are leading us to consider their combined and potentially extreme consequences, particularly regarding hydrological processes, which can be modeled using a generalized extreme value (GEV) distribution. Most of the GEV models were based on a stationary assumption for hydrological processes, in contrast to the nonstationary reality due to climate change and human activities. In this paper, we present the nonstationary generalized extreme value (NSGEV) distribution and use it to investigate the risk of Niangziguan Springs discharge decreasing to zero. Rather than assuming the location, scale, and shape parameters to be constant as one might do for a stationary GEV distribution analysis, the NSGEV approach can reflect the dynamic processes by defining the GEV parameters as functions of time. Because most of the GEV model is designed to evaluate maxima (e.g. flooding, represented by positive numbers), and spring discharge cessation is a ?minima’, we deduced an NSGEV model for minima by applying opposite numbers, i.e. negative instead of positive numbers. The results of the model application to Niangziguan Springs showed that the probability of zero discharge at Niangziguan Springs will be 1/80 in 2025, and 1/10 in 2030. After 2025, the rate of decrease in spring discharge will accelerate, and the probability that Niangziguan Springs will cease flowing will dramatically increase. The NSGEV model is a robust method for analysing karst spring discharge. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
34.
利用2005年安排在临泽边缘绿洲沙地农田的长期施肥定位试验,研究不同用量有机肥、化肥、有机肥和化肥配施对绿洲沙地土壤肥力及有机碳积累的影响。试验包括高量有机肥单施(M3),氮磷化肥单施(NP3),低、中、高量氮磷钾化肥单施(NPK1,NPK2,NPK3),及低、中、高量氮磷钾化肥配施高、中、低量有机肥9个处理(NPK1M3,NPK2M2,NPK3M1),测定分析10年后不同施肥处理耕层(0~20 cm)土壤物理化学性状特征及有机碳动态。结果表明:施有机肥及有机无机配施处理较单施化肥处理容重下降0.13 g·cm-3,田间持水量提高6.7%,单施有机肥、有机无机配施较单施化肥,土壤有机碳(SOC)和全氮含量分别提高64.8%、36.3%和64.9%、49.5%。高量施用氮磷化肥和氮磷钾化肥处理全磷含量最高,有机肥及有机无机配施较单施化肥有效氮含量显著增加,有机无机配施及高量施用磷肥土壤有效磷积累明显,高量施用有机肥能显著提升有效钾含量。连续施肥处理10年后,SOC含量提高了1.68~2.84倍,土壤全氮、全磷、碱解氮及有效磷均有一定程度的提高,但单施化肥及有机肥与氮磷化肥配施有效钾含量下降。SOC的积累速率单施化肥、有机无机配施,单施有机肥处理分别为0.27、0.59,0.87 g·kg-1·a-1。增施有机肥、适量减少化肥投入、氮磷钾化肥的平衡施用是绿洲沙地农田土壤肥力持续提升的施肥管理对策。  相似文献   
35.
关键金属元素分析测试技术方法应用进展   总被引:7,自引:5,他引:2  
以稀有、稀散、稀土、铂族元素为主体的战略性关键金属矿产资源,在新材料、新能源和信息技术等新兴产业中发挥着越来越关键的作用。随着我国关键矿产资源地质调查的不断深入,关键金属元素以其赋存基体复杂、不同矿物含量差异大、化学性质不稳定等特点对分析测试技术提出了新的挑战。本文根据化学组成不同,对关键金属元素主要赋存基体进行了分类,主要分为硅酸盐、碳酸盐、硫酸盐、钨酸盐、磷酸盐、氧化物、硫化物、卤化物等。对于不同的基体岩石矿物,通常采用酸溶法(硝酸-氢氟酸组合、王水)或碱熔法等传统溶样方法进行化学消解。评述了当前关键金属元素测试常用的电子探针、电感耦合等离子体质谱、电感耦合等离子体发射光谱、X射线荧光光谱等仪器的特点及应用,总结了关键金属元素分析过程中出现的样品难溶解、回收率不完全、测试过程氧化物和同质异位素干扰、样品和标准基体不一致等常见问题,并提出了相应的解决方案。微区原位分析凭借其高效率、低成本、高空间分辨率的优势,以及野外现场分析凭借其简单快速、贴近野外工作的特点是关键金属元素测试技术发展的主要趋势。  相似文献   
36.
史富全 《探矿工程》2020,47(11):37-43
油气井发生溢流或井喷后,立即关闭防喷器,关井期间防喷器需经受关井产生的水击压力作用。本文在对井喷关井水击的传播物理特征分析的基础上,推导直接关井水击压力计算公式,综合考虑井筒流体含气率、气液两相流型、固相类型等对水击波速的影响,推导水击波在气、液、固三相混合流体中传播速度计算公式,并通过算例对水击波速影响因素进行分析。计算表明水击波速对含气率变化非常敏感,钻井液含气率在0~0.001的时候,水击波速几乎是发生了突变,水击波速在含气率为0.001时仅为385 m/s,相比纯钻井液情况下降了67%,而钻井液固相含量、套管的内径和壁厚对水击波传播速度影响较小。  相似文献   
37.
位于中国和尼泊尔边境的西藏樟木口岸是国家一类陆路通商口岸,也是西藏最大的边贸中心口岸。2015年尼泊尔大地震之后,西藏樟木口岸因多次发生滑坡灾害,而导致口岸关闭。为了调查樟木口岸区域滑坡灾害的分布和变形情况及更好的服务于区域减灾防灾,利用InSAR技术对覆盖该区域的Sentinel-1A和ALOS-2两种卫星影像数据进行了处理,并通过分析视线向年均形变速率图,圈定了17处疑似滑坡,并对其中的5处典型滑坡进行时间序列形变特征分析,监测识别出的滑坡基本沿318国道所在一侧的波曲河左岸分布。InSAR调查结果表明受地震影响樟木地区的滑坡多分布在沿波曲河左岸的陡峭山体上,中尼公路迪斯岗至友谊桥段的古滑坡出现了局部复活的现象,同时樟木镇居民所在的城区也发育有扎美拉山危岩体崩塌滑坡灾害。   相似文献   
38.
We investigate the spatial and temporal englacial and subglacial processes associated with a temperate glacier resting on a deformable bed using the unique Glacsweb wireless in situ probes (embedded in the ice and the till) combined with other techniques [including ground penetrating radar (GPR) and borehole analysis]. During the melt season (spring, summer and autumn), high surface melt leads to high water pressures in the englacial and subglacial environment. Winter is characterized by no surface melting on most days (‘base’) apart from a series of positive degree days. Once winter begins, a diurnal water pressure cycle is established in the ice and at the ice/sediment interface, with direct meltwater inputs from the positive degree days and a secondary slower englacial pathway with a five day lag. This direct surface melt also drives water pressure changes in the till. Till deformation occurred throughout the year, with the winter rate approximately 60% that of the melt season. We were able to show the bed comprised patches of till with different strengths, and were able to estimate their size, relative percentage and temporal stability. We show that the melt season is characterized by a high pressure distributed system, and winter by a low pressure channelized system. We contrast this with studies from Greenland (overlying rigid bedrock), where the opposite was found. We argue our results are typical of soft bedded glaciers with low englacial water content, and suggest this type of glacier can rapidly respond to surface-driven melt. Based on theoretical and field results we suggest that the subglacial hydrology comprises a melt season distributed system dominated by wide anastomosing broad flat channels and thin water sheets, which may become more channelized in winter, and more responsive to changes in meltwater inputs. © 2019 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.  相似文献   
39.
This paper resolves the origin of clay hummock micro-topography in seasonal wetlands of the Drakensberg Foothills, providing a review and appraisal of previously-suggested mechanisms of hummock formation in the context of new field and laboratory data. Field surveys revealed neo-formation of clay hummocks in a river channel that had been abandoned in c.1984. Fresh earthworm castings were located atop hummocks protruding from inundated abandoned channel margins. Earthworm castings, and sediment cores taken in hummocks and adjacent hollows, were analysed for soil-adsorbed carbon and nitrogen using an HCN analyser, and for 210Pb activity using alpha-geochronology. 210Pb activity profiles suggest relative enrichment of the isotope in hummocks, and relative depletion in adjacent hollows. Earthworm castings are characterised by very high 210Pb activity, as well as high C and N contents. Hummocks have significantly higher C and N contents than adjacent hollows. Results suggest that it is the foraging activity of earthworms in litter-rich seasonal wetland hollows, and repeated excretion of castings atop adjacent hummocks, that is responsible for the elemental enrichment observed. The paper presents a conceptual model of hummock formation in wetlands through interactions between hydrogeomorphology and earthworm activity, and illustrates a mechanism of biogeomorphic inheritance through which ordered patterns of preferential flow can emerge in ecosystems. Further implications of hummock formation and nodal accumulation of nutrients are considered in relation to wetland resilience and regulatory ecosystem service provision.© 2018 John Wiley & Sons, Ltd.  相似文献   
40.
以章宁1地热井的研究为例,在分析地热水水文地球化学特征基础上,对地热水的化学成分形成进行了研究,并通过与相对补给径流区的西曹范、章桃1地下水水化学特征的比较,研究其演化机理。综合分析认为地热水为沉积岩溶滤水,属于中度变质水,地下水流经火成岩侵入体时溶解了大量的Cl~-及F~-,HSiO~-_3等微量元素,次为地下水与沿文祖断裂上升的深部热液的混合,导致地热水化学类型的改变。深部热液的水化学成分与济南东地热水与深部热液的混合比例有待进一步研究。  相似文献   
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